Weber, Lothar; Frebel, Matthias; Boese, Roland:
Transition metal substituted diphosphenes. 11. [1 + 4]-Cycloaddition of diphosphenes with acrolein: synthesis and structure of dihydro-1,2l5-oxaphospholes with exocyclic P:P bond.
1987
In: Angewandte Chemie, Jg. 99 (1987), Heft 10, S. 1045 - 1046
Artikel/Aufsatz in Zeitschrift / Fach: Chemie
Titel:
Transition metal substituted diphosphenes. 11. [1 + 4]-Cycloaddition of diphosphenes with acrolein: synthesis and structure of dihydro-1,2l5-oxaphospholes with exocyclic P:P bond.
Autor(in):
Weber, Lothar; Frebel, Matthias; Boese, Roland im Online-Personal- und -Vorlesungsverzeichnis LSF anzeigen
Erscheinungsjahr:
1987
Erschienen in:
Angewandte Chemie, Jg. 99 (1987), Heft 10, S. 1045 - 1046
ISSN:

Abstract:

Reaction of diphospheneiron, Cp(CO)2FeP:PR [Cp = pentamethylcyclopentadienyl, R = 2,4,6-(Me3C)3C6H2] with acrolein gave oxaphosphole iron carbonyl complex I, contg. an exocyclic P:P double bond. Crystal structure of I was detd.