Weber, Lothar; Kirchhoff, Ralf; Boese, Roland:

Insertion of the P:C-functionality of (pentamethylcyclopentadienyl)(dicarbonyl)[1,3,3-tris(trimethylsilyl)-h1-1,2-diphosphaallyl]iron into a C5Me5 C-H bond: formation of a chelating (h1-P,h5-C5)-3-tetramethylcyclopentadienyl-1,2-diphosphapropanido ligand.

In: Journal of the Chemical Society, Chemical Communications, (1992) ; Nr. 17, S. 1182-1184
ISSN: 0022-4936
Zeitschriftenaufsatz / Fach: Chemie
Abstract:
Heating a methylcyclohexane soln. of [(h5-C5Me5)(CO)2FeP(SiMe3)P:C(SiMe3)2] gives rise to the insertion of the P:C-moiety into the CH-bond of a ring Me group forming the chelate complex I, which is trapped by (Z-cyclooctene)Cr(CO)5 and fully characterized as its Cr(CO)5 adduct II.

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