Weber, Lothar; Kirchhoff, Ralf; Boese, Roland:
Insertion of the P:C-functionality of (pentamethylcyclopentadienyl)(dicarbonyl)[1,3,3-tris(trimethylsilyl)-h1-1,2-diphosphaallyl]iron into a C5Me5 C-H bond: formation of a chelating (h1-P,h5-C5)-3-tetramethylcyclopentadienyl-1,2-diphosphapropanido ligand.
1992
In: Journal of the Chemical Society, Chemical Communications, Heft 17, S. 1182 - 1184
Artikel/Aufsatz in Zeitschrift / Fach: Chemie
Titel:
Insertion of the P:C-functionality of (pentamethylcyclopentadienyl)(dicarbonyl)[1,3,3-tris(trimethylsilyl)-h1-1,2-diphosphaallyl]iron into a C5Me5 C-H bond: formation of a chelating (h1-P,h5-C5)-3-tetramethylcyclopentadienyl-1,2-diphosphapropanido ligand.
Autor(in):
Weber, Lothar; Kirchhoff, Ralf; Boese, Roland im Online-Personal- und -Vorlesungsverzeichnis LSF anzeigen
Erscheinungsjahr:
1992
Erschienen in:
Journal of the Chemical Society, Chemical Communications, Heft 17, S. 1182 - 1184
ISSN:

Abstract:

Heating a methylcyclohexane soln. of [(h5-C5Me5)(CO)2FeP(SiMe3)P:C(SiMe3)2] gives rise to the insertion of the P:C-moiety into the CH-bond of a ring Me group forming the chelate complex I, which is trapped by (Z-cyclooctene)Cr(CO)5 and fully characterized as its Cr(CO)5 adduct II.