Novel rearrangements and formation of 2,5-dihydro-1,2,5-oxoniastannaboratoles via methanolysis of zwitterionic h2-(alkyn-1-yl-borate)alkenyltin compounds.
In: Chemistry of Heterocyclic Compounds (New York)(Translation of Khimiya Geterotsiklicheskikh Soedinenii), Jg. 35 (2000) ; Nr. 9, S. 1041-1051
Zeitschriftenaufsatz / Fach: Chemie
Organo-substituted 2,5-dihydro-1,2,5-oxoniastannaboratoles I (R = Et, R1 = nPr, CH2NMe2; R = iPr, R1 = Et) were prepd. by methanolysis of zwitterionic h2-(alkyn-1-ylborate)alkenyltin compds. Analogously, the bis[h2-(alkyn-1-yl-borate)alkenyltin] deriv. reacts with an excess of methanol to give a dimeric MeO-bridged 2,5-dihydro-1,2,5-oxoniastannaboratole II. Various intermediates could be identified by NMR spectroscopy, and the mol. structure of II was detd. by x-ray anal. The structures of several products of the methanolysis indicate that protolysis of an Sn-C: bond occurs first, followed by an MeO/alkenyl exchange reaction.
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