Yalpani, Mohamed; Boese, Roland; Koester, Roland:
Boron compounds. 78. Bis(9-borabicyclo[4.2.1]nonane).
In: Chemische Berichte (Chem.Ber.), Jg. 121 ; Heft 2, S. 287 - 293
Zeitschriftenaufsatz / Fach: Chemie
Boron compounds. 78. Bis(9-borabicyclo[4.2.1]nonane).
Yalpani, Mohamed; Boese, Roland im Online-Personal- und -Vorlesungsverzeichnis LSF anzeigen; Koester, Roland
Erschienen in:
Chemische Berichte (Chem.Ber.), Jg. 121 ; Heft 2, S. 287 - 293


Treating bis(9-borobicyclo[3.3.1]nonane) (I) with quinuclidine (II) in hydrocarbon solvents at 150 Deg gives quinuclidino-9-borabicyclo[3.3.1]- (III) and -[4.2.1]nonane (IV), which are sepd. by fractional crystn. after rapid cooling. The differing intermol. interactions found in cryst. III and IV by x-ray anal. reflect some of their solid-state properties. IV reacts with BF3.OEt2 to give an approx. equimolar mixt. of syn- (V) and anti-bis(9-borabicyclo[4.2.1]nonane) (VI). IV, and therefore VI, are also prepd. by adding II to the initial hydroboration product mixt. obtained from 1,5-cyclooctadiene and THF.BH3.