Harder, Sjoerd; Boersma, Jaap; Brandsma, Lambert; Van Mier, Guido P. M.; Kanters, Jan A.:

The molecular structure of 1-lithio-2-methoxybenzene in the solid state and in solution.

In: Journal of Organometallic Chemistry, Jg. 364 (1989) ; Nr. 1-2, S. 1-15
ISSN: 0022-328X
Zeitschriftenaufsatz / Fach: Chemie
The crystal structure of 1-lithio-2-methoxybenzene has been detd. at 298 K by single crystal x-ray techniques. Each unit-cell contains two centrosym. related tetrameric units which show Li...HC interactions with each other. Its structure in soln. has been detd. by NMR spectroscopy and assocn. measurements. The influence of various Lewis bases on the soln. structure has been studied.