Structure of a Benzylcalcium Diastereomer: An Initiator for the Anionic Polymerization of Styrene.
In: Organometallics, Jg. 20 (2001) ; Nr. 6, S. 1044-1046
Zeitschriftenaufsatz / Fach: Chemie
A new dibenzylcalcium compd. with chiral anionic centers was prepd. and was structurally characterized. The compd., which shows slow inversion of the chiral carbanions, is an active initiator for the living polymn. of styrene.