Convergence of multipole expanded intermolecular interaction energies for Gaussian-type-function and Slater-type-function basis sets.
It is shown that the multipole expansion of each order of the polarization series converges for large enough intermol. distances when finite basis sets of Gaussian or Slater-type functions are used to approx. mol. response properties. Convergence of the multipole expansion for each order of the polarization series does not imply convergence of the polarization series itself. A corresponding convergence condition is extd. from the general perturbation theory in a finite-dimensional space and is applied to the H + H+ problem.
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