Jansen, Georg; Hess, Bernd A.; Wormer, Paul E. S.:
Theoretical investigation of the rovibrational fine-structure spectrum of argon-imidogen in its electronic ground state.
1993
In: Chemical Physics Letters, Jg. 214 (1993), Heft 1, S. 103 - 108
Artikel/Aufsatz in Zeitschrift / Fach: Chemie
Titel:
Theoretical investigation of the rovibrational fine-structure spectrum of argon-imidogen in its electronic ground state.
Autor(in):
Jansen, Georg im Online-Personal- und -Vorlesungsverzeichnis LSF anzeigen; Hess, Bernd A.; Wormer, Paul E. S.
Erscheinungsjahr
1993
Erschienen in:
Chemical Physics Letters, Jg. 214 (1993), Heft 1, S. 103 - 108
ISSN

Abstract:

Based on an ab initio potential energy surface for the X3A'' ground state of the Ar-NH van der Waals complex its rovibrational fine-structure spectrum has been calcd. The authors find four Ar-NH stretching vibrational modes with the NH radical in a nearly unperturbed n = 0 rotational state and one vibrational mode with NH in its first excited rotational level n = 1. The results are discussed and interpreted by means of pseudodiat. model calcns.