Schmidt, Torsten C.; Steinbach, Klaus; Buetehorn, Ulf; Heck, Kerstin; Volkwein, Ute; Stork, Gottfried:
Synthesis of reference substances for highly polar metabolites of nitroaromatic compounds.
1999
In: Chemosphere (Chemosphere), Jg. 38 (1999), Heft 13, S. 3119 - 3130
Artikel/Aufsatz in Zeitschrift1999Chemie
Titel:
Synthesis of reference substances for highly polar metabolites of nitroaromatic compounds.
Autor(in):
Schmidt, Torsten C.LSF; Steinbach, Klaus; Buetehorn, Ulf; Heck, Kerstin; Volkwein, Ute; Stork, Gottfried
Erscheinungsjahr
1999

Abstract:

In order to identify polar and hydrophilic degrdn. products of nitroarom. compds. in water and soil samples, nitroarom. compds. were prepd. and characterized as ref. stds. E.g., 4-amino-2,6-dinitrobenzyl alc. was prepd. regioselectively in 60% yield as a 19:1 mixt. with 6-amino-2,4-dinitrotoluene by redn. of 2,4,6-trinitrobenzyl alc. with Ti3+ in the presence of EDTA. Many of the newly synthesized analytes were found in various water samples from a former ammunition plant.