Hasenbein, Norbert; Bandermann, Friedhelm:
Polymerization of isobutene with vanadium oxytrichloride in heptane.
1987
In: Makromolekulare Chemie (Makromol.Chem.), Jg. 188 (1987), Heft 1, S. 83 - 91
Artikel/Aufsatz in Zeitschrift / Fach: Chemie
Titel:
Polymerization of isobutene with vanadium oxytrichloride in heptane.
Autor(in):
Hasenbein, Norbert; Bandermann, Friedhelm im Online-Personal- und -Vorlesungsverzeichnis LSF anzeigen
Erscheinungsjahr:
1987
Erschienen in:
Makromolekulare Chemie (Makromol.Chem.), Jg. 188 (1987), Heft 1, S. 83 - 91
ISSN:

Abstract:

The polymn. of isobutene [115-11-7] with VOCl3 in heptane was investigated. In contrast to reports in the literature, the polymn. only started upon irradn. with light or when naphthalene [91-20-3] was added, and it ceased when the light source was switched off. The reaction proceeded like a photoinitiated cationic polymn., and the claim of a living system was not corroborated.