Klahn, Juergen; Bandermann, Friedhelm:
Optimizing procedure of reaction of living polymers. Theoretical considerations about molecular weight distributions of living polymers in a periodically stirred tank reactor.
1979
In: Angewandte Makromolekulare Chemie, Band 83 (1979), S. 1 - 19
Artikel/Aufsatz in Zeitschrift1979Chemie
Titel:
Optimizing procedure of reaction of living polymers. Theoretical considerations about molecular weight distributions of living polymers in a periodically stirred tank reactor.
Autor(in):
Klahn, Juergen; Bandermann, FriedhelmLSF
Erscheinungsjahr
1979

Abstract:

An equation for calcg. the mol. wt. distribution of a living polymer in a periodically-stirred tank reactor was derived. Polymer inhomogeneity was detd. under various reaction conditions. The use of a d-functional type of control of the vol. flow rate of the product stream theor. enables the prodn. of polymers with nonuniformity 0-.... A multimodel distribution function was a special feature of the periodic reactor control.