Speikamp, Hans Dieter; Bandermann, Friedhelm:
Group-transfer polymerization of methyl methacrylate in acetonitrile. 2. Initiation by trimethylsilyl cyanide.
1988
In: Makromolekulare Chemie (Makromol.Chem.), Jg. 189 (1988), Heft 2, S. 437 - 445
Artikel/Aufsatz in Zeitschrift1988Chemie
Titel:
Group-transfer polymerization of methyl methacrylate in acetonitrile. 2. Initiation by trimethylsilyl cyanide.
Autor(in):
Speikamp, Hans Dieter; Bandermann, FriedhelmLSF
Erscheinungsjahr
1988

Abstract:

Results of group-transfer polymn. of Me methacrylate in MeCN with Et4N+CN- and tris(dimethylamino)sulfonium difluorotrimethylsilicate (I) as catalysts and Me3SiCN as initiator were presented. Both catalysts behaved similarly with respect to catalysis of the initiation and the propagation step and of the termination of the growing chains with the solvent, I being more active than Et4N+CN-.