Schrader, Thomas; Steglich, Wolfgang:
Phosphorus analogs of amino acids. II. Synthesis of a-amino phosphonic acids and a-amino phosphinic acids via the corresponding N-acylimino derivatives.
1989
In: Synthesis, Heft 2, S. 97 - 101
Artikel/Aufsatz in Zeitschrift1989Chemie
Titel:
Phosphorus analogs of amino acids. II. Synthesis of a-amino phosphonic acids and a-amino phosphinic acids via the corresponding N-acylimino derivatives.
Autor(in):
Schrader, ThomasLSF; Steglich, Wolfgang
Erscheinungsjahr
1989
Erschienen in:
Titel:
Synthesis
in:
Heft 2, S. 97 - 101
ISSN:

Abstract:

Acyliminomethylphosphonic and acyliminomethylphosphinic esters, usually formed in situ from the corresponding acylamino(bromo)methyl compds., react with higher order mixed cuprates to yield, after hydrolysis, C-substituted aminomethylphosphonic acids and aminomethylphosphinic acids, resp.