Siesler, H.w.; Tittle, B.:
New catalytic system for the polymerization of THF.
1975
In: Polymer (Polymer), Jg. 16 (1975), Heft 7, S. 548 - 549
Artikel/Aufsatz in Zeitschrift / Fach: Chemie
Titel:
New catalytic system for the polymerization of THF.
Autor(in):
Siesler, H.w. im Online-Personal- und -Vorlesungsverzeichnis LSF anzeigen; Tittle, B.
Erscheinungsjahr
1975
Erschienen in:
Polymer (Polymer), Jg. 16 (1975), Heft 7, S. 548 - 549
ISSN

Abstract:

Treatment of 4 ml THF [109-99-9] with .apprx.0.1 g of the orange product contg. P(CN)3 [1116-01-4] and acetonitrile [75-05-8], prepd. by treating PCl3 with AgCN 2 hr in acetonitrile, evapn. of solvent, and leaving the product 24 hr in air, gave after .apprx.1 hr a transparent yellow-brown solid. After 2 days 43-54% cryst. high mol. wt. poly(THF) was obtained.