Measurement of molecular orientation in uniaxially drawn polyacrylonitrile films.

In: Makromolekulare Chemie (Makromol.Chem.), Jg. 176 (1975) ; Nr. 8, S. 2451-2458
ISSN: 0025-116X
Zeitschriftenaufsatz / Fach: Chemie
Orientation parameters related to the C.tplbond.N stretching vibration and the CH2 deformation vibration absorption bands in the three film coordinate directions were obtained from 3-dimensional measurements on uniaxially drawn polyacrylonitrile [25014-41-9] films with linearly polarized ir radiation. The ir data were combined with x-ray diffraction measurements to characterize the type and degree of mol. orientation.