Hubinger, Regina; Pawelke, Gottfried:
Trifluoromethylation of carbon and boron with CF3SiMe3/NMe4F: formation of NMe4[trans-CF3-CF:CFB(CF3)3].
2002
In: Journal of Fluorine Chemistry (J.Fluorine Chem.), Jg. 115 (2002), Heft 2, S. 115 - 118
Artikel/Aufsatz in Zeitschrift / Fach: Chemie
Titel:
Trifluoromethylation of carbon and boron with CF3SiMe3/NMe4F: formation of NMe4[trans-CF3-CF:CFB(CF3)3].
Autor(in):
Hubinger, Regina; Pawelke, Gottfried
Erscheinungsjahr
2002
Erschienen in:
Journal of Fluorine Chemistry (J.Fluorine Chem.), Jg. 115 (2002), Heft 2, S. 115 - 118
ISSN

Abstract:

Trimethylamine-trifluoroethenyl-bis(trifluoromethyl)borane [F2C:CF(CF3)2B.NMe3] reacts with NMe4[(CF3)2SiMe3] in THF soln. to form trimethylamine-bis(trifluoromethyl)pentafluoropropenylborane [trans-CF3-CF:CF(CF3)2B.NMe3], the fluoroborate NMe4[trans-CF3-CF:CF(CF3)2BF], the novel borates NMe4[trans-CF3-CF:CFB(CF3)3] and NMe4[cyclo-(CF3)2B-CF2-CF-CF2-CF3]. [on SciFinder (R)]