De Jong, A.f.; Kentgens, A.p.m.; Veeman, W.s.:

Two-dimensional exchange NMR in rotating solids: a technique to study very slow molecular reorientations.

In: Chemical Physics Letters, Jg. 109 (1984) ; Nr. 4, S. 337-342
ISSN: 0009-2614
Zeitschriftenaufsatz / Fach: Chemie
A 2D expts. capable of detecting very slow mol. reorientations is proposed, which makes use of spinning sidebands obsd. in magic-angle-spinning spectra. An expression describing the spinning side band intensities of the 2D spectrum is given. The expt. is applied to dimethylsulfone. Exptl. and calcd. spectra show agree.