Diesveld, J.w.; Menger, E.m.; Edzes, H.t.; Veeman, W.s.:
High-resolution solid-state phosphorus-31 nuclear magnetic resonance of some triphenylphosphine transition-metal complexes.
1980
In: Journal of the American Chemical Society (J.Am.Chem.Soc.), Jg. 102 (1980), Heft 27, S. 7935 - 7936
Artikel/Aufsatz in Zeitschrift / Fach: Chemie
Titel:
High-resolution solid-state phosphorus-31 nuclear magnetic resonance of some triphenylphosphine transition-metal complexes.
Autor(in):
Diesveld, J.w.; Menger, E.m.; Edzes, H.t.; Veeman, W.s. im Online-Personal- und -Vorlesungsverzeichnis LSF anzeigen
Erscheinungsjahr:
1980
Erschienen in:
Journal of the American Chemical Society (J.Am.Chem.Soc.), Jg. 102 (1980), Heft 27, S. 7935 - 7936
ISSN:

Abstract:

High resoln. solid state 31P NMR spectra are reported of 4 representative examples of metal phosphine complexes. The spectra from a Rh complex (Wilkinson's catalyst) and Cu complexes show splittings due to 31P-metal coupling. In spite of the Cu quadrupole interaction, the 31P NMR lines of the Cu complexes are narrow (.apprx.2 ppm). For 1 Cu complex the splittings between the lines of the 31P quartet are unequal. Also the spectrum of a Au cluster is reported.