Van der Mijden, J.a.m.; Janssen, R.; Veeman, W.s.:

Analytical description of the I = 5/2 quadrupole nutation experiment.

In: Molecular Physics (Mol.Phys.), Jg. 69 (1990) ; Nr. 1, S. 53-64
ISSN: 0026-8976
Zeitschriftenaufsatz / Fach: Chemie
The theory of nutation NMR for a quadrupolar nucleus with spin quantum I = 5/2 is presented in an exact, anal. way. It is shown that the nutation spectrum is described by 9 different frequencies each dependent on the orientation of the quadrupole tensor relative to the external field. The frequencies are calcd. from the eigenvalues of a 6th-degree secular equation that is reduced to 2 secular equations of order 3. This redn. is obtained by a transformation of bases. An extension of the nutation expt., x.hivin.x-nutation, is compared with the std. technique. The theor. spectra are compared with exptl. 27Al spectra of NH4Al(SO4)2.12H2O and zeolite NaA.