Handwerk, V.; Zellner, R.:
Kinetics and energetics of the reaction chlorine monoxide + oxygen(1D6) -> chlorine trioxide.
1986
In: Berichte der Bunsen-Gesellschaft, Jg. 90 (1986), Heft 1, S. 92 - 96
Artikel/Aufsatz in Zeitschrift / Fach: Chemie
Titel:
Kinetics and energetics of the reaction chlorine monoxide + oxygen(1D6) -> chlorine trioxide.
Autor(in):
Handwerk, V.; Zellner, R. im Online-Personal- und -Vorlesungsverzeichnis LSF anzeigen
Erscheinungsjahr:
1986
Erschienen in:
Berichte der Bunsen-Gesellschaft, Jg. 90 (1986), Heft 1, S. 92 - 96
ISSN:

Abstract:

The rate coeff. for reaction between ClO (2P) and O2 (1Dg) was measured using a flow/flash photolysis technique. An upper limit of k1 ? 3*10-15 cm3/s at 298 K was found. The formation of sym. ClO3 (2A1) as a product is spin and orbital symmetry allowed but is probably prevented by an activation barrier and by equil. constraints. The rate coeff. for quenching of O2 (1D) is allowed but is probably prevented by an activation barrier and by equil. constraints. The rate coeff. for quenching of O2 (1D) by Cl2 is 2*10-17 cm3/s at 298 K.