Laser photolysis/resonance fluorescence study of the rate constants for the reactions of hydroxyl radicals with ethene and propene.
In: Journal of Physical Chemistry (J.Phys.Chem.), Jg. 88 (1984) ; Nr. 5, S. 984-990
Zeitschriftenaufsatz / Fach: Chemie
Abs. rate consts. for the title reactions were measured using excimer laser photolysis to generate .bul.OH radicals and time-resolved resonance fluorescence as its monitor. Both reaction rates were pressure dependent, and show fall-off behavior at high pressure.